Deep Cycle Battery FAQ
The links below are on this page - you can also just scroll down if
you want to read them all.
- What is a Battery?
- Types of Batteries
- Battery Lifespan
- Starting, Marine, or Deep Cycle?
- Deep Cycle Battery as a Starting Battery?
- What Batteries are made of
- Industrial Batteries (fork lift type)
- Sealed Batteries
- Battery Size Codes
- Gel Cells (and why we don't like them)
- AGM Batteries (and why we do like them)
- Temperature Effects
- Cycles vs Lifespan
- Amp Hours - what are they?
- Battery Voltages
- Battery Charging (Here is where we get into the real meat)
- Charge Controllers (for wind/solar)
- Mini Factoids - Some small facts about batteries
The subject of batteries could take up many pages. All we have room
for here is a basic overview of batteries commonly used with
photovoltaic power systems. These are nearly all various variations of
Lead-Acid batteries. For a very brief discussion on the advantages and
disadvantages of these and other types of batteries, such as NiCad, NiFe
(Nickel-Iron), etc. These are sometimes referred to as "deep
discharge" or "deep cell" batteries. The correct term is deep cycle.
A printable version of this page will be available in Adobe PDF
format when we finish updating this page for downloading and printing:
Most of the charts have small images for faster downloading. To see the
full size picture, just click on the small one.
Battery History
Although
Alessandro Volta in Italy is usually credited with being the
inventor of the modern battery (Silver-Zinc), ancient cells have been
discovered in Sumerian ruins, origin around 250 BC.
The first evidence of batteries comes from archaeological digs in
Baghdad, Iraq. This first "battery" was dated to around 250 B.C. and may
have been used in simple operations to electroplate objects with a thin
layer of metal, much like the process used now to plate inexpensive gold
and silver jewelry. Possibly one of the first uses for batteries,
although there is some dispute among scholars.
Wikipedia entry for Baghdad Battery.
Batteries were re-discovered much later by Alessandro Volta after
which the unit of electrical potential was named, the volt. The jar was
found in Khujut Rabu just outside Baghdad and is composed of a clay jar
with a stopper made of asphalt. Sticking through the asphalt is an iron
rod surrounded by a copper cylinder. When filled with vinegar - or any
other electrolytic solution - the jar produces about 1.1 volts.
A battery, in concept, can be any device that stores energy for later
use. A rock, pushed to the top of a hill, can be considered a kind of
battery, since the energy used to push it up the hill (chemical energy,
from muscles or combustion engines) is converted and stored as potential
kinetic energy at the top of the hill. Later, that energy is released as
kinetic and thermal energy when the rock rolls down the hill. Not real
practical for everyday use though.
Common use of the word, "battery" in electrical terms, is limited to
an electrochemical device that converts chemical energy into
electricity, by a galvanic cell. A galvanic cell is a fairly simple
device consisting of two electrodes of different metals or metal
compounds (an anode and a cathode) and an electrolyte (usually acid, but
some are alkaline) solution. A "Battery" is two or more of those cells
in series, although many types of single cells are usually referred to
as batteries - such as flashlight batteries.
As noted above, a battery is an electrical storage device. Batteries
do not make electricity, they store it, just as a water tank stores
water for future use. As chemicals in the battery change, electrical
energy is stored or released. In rechargeable batteries this process can
be repeated many times. Batteries are not 100% efficient - some energy
is lost as heat and chemical reactions when charging and discharging. If
you use 1000 watts from a battery, it might take 1050 or 1250 watts or
more to fully recharge it.
Internal Resistance
Part - or most - of the loss in charging and discharging batteries is
due to internal resistance. This is converted to heat, which is why
batteries get warm when being charged up. The lower the internal
resistance, the better.
Slower charging and discharging rates are more efficient. A battery
rated at 180 amp-hours over 6 hours might be rated at 220 AH at the
20-hour rate, and 260 AH at the 48-hour rate. Much of this loss of
efficiency is due to higher internal resistance at higher amperage rates
- internal resistance is not a constant - kind of like "the more you
push, the more it pushes back".
Typical efficiency in a lead-acid battery is 85-95%, in alkaline and
NiCad battery it is about 65%. True deep cycle AGM's (such as Concorde
and Deka) can approach 98%.
Practically all batteries used in PV and all but the smallest backup
systems are Lead-Acid type batteries. Even after over a century of use,
they still offer the best price to power ratio. A few systems use NiCad,
but we do not recommend them except in cases where extremely cold
temperatures (-50 F or less) are common. They are expensive to buy, and
very expensive to dispose of due the the hazardous nature of Cadmium.
We have had almost no direct experience with the NiFe (alkaline)
batteries, but from what we have learned from others we do not not
recommend them - one major disadvantage is that there is a large voltage
difference between the fully charged and discharged state. Another
problem is that they are very inefficient - you lose from 30-40% in heat
just in charging and discharging them. Many inverters and charge
controls have a hard time with them. It appears that the only current
source for new cells seems to be from Hungary.
An important fact is that ALL of the batteries commonly used in deep
cycle applications are Lead-Acid. This includes the standard flooded
(wet) batteries, gelled, and AGM. They all use the same chemistry,
although the actual construction of the plates etc varies.
NiCads, Nickel-Iron, and other types are found in a few systems, but
are not common due to their expense, environmental hazards, and/or poor
efficiency.
Batteries are divided in two ways, by application (what they are used
for) and construction (how they are built). The major applications are
automotive, marine, and deep-cycle. Deep-cycle includes solar electric
(PV), backup power, and RV and boat "house" batteries. The major
construction types are flooded (wet), gelled, and AGM (Absorbed Glass
Mat). AGM batteries are also sometimes called "starved electrolyte" or
"dry", because the fiberglass mat is only 95% saturated with Sulfuric
acid and there is no excess liquid.
Flooded may be standard, with removable caps, or the so-called
"maintenance free" (that means they are designed to die one week after
the warranty runs out). All gelled are sealed and are "valve regulated",
which means that a tiny valve keeps a slight positive pressure. Nearly
all AGM batteries are sealed valve regulated (commonly referred to as "VRLA"
- Valve Regulated Lead-Acid). Most valve regulated are under some
pressure - 1 to 4 psi at sea level.
The lifespan of a deep cycle battery will vary considerably with how
it is used, how it is maintained and charged, temperature, and other
factors. In extreme cases, it can vary to extremes - we have seen L-16's
killed in less than a year by severe overcharging, and we have a large
set of surplus telephone batteries that sees only occasional (5-10 times
per year) heavy service that are now over 25 years old. We have seen
gelled cells destroyed in one day when overcharged with a large
automotive charger. We have seen golf cart batteries destroyed without
ever being used in less than a year because they were left sitting in a
hot garage without being charged. Even the so-called "dry charged"
(where you add acid when you need them) have a shelf life of 18 months
at most. They are not totally dry - they are actually filled with acid,
the plates formed and charged, then the acid is dumped out.
These are some typical (minimum - maximum) typical expectations for
batteries if used in
deep cycle service. There are so many variables, such as depth
of discharge, maintenance, temperature, how often and how deep cycled,
etc. that it is almost impossible to give a fixed number.
- Starting: 3-12 months
- Marine: 1-6 years
- Golf cart: 2-7 years
- AGM deep cycle: 4-7 years
- Gelled deep cycle: 2-5 years
- Deep cycle (L-16 type etc): 4-8 years
- Rolls-Surrette premium deep cycle: 7-15 years
- Industrial deep cycle (Crown and Rolls 4KS series): 10-20+ years
- Telephone (float): 2-20 years. These are usually special purpose
"float service", but often appear on the surplus market as "deep
cycle". They can vary considerably, depending on age, usage, care,
and type.
- NiFe (alkaline): 5-35 years
- NiCad: 1-20 years
- Starting (sometimes called SLI, for starting,
lighting, ignition) batteries are commonly used to start and run
engines. Engine starters need a very large starting current for a
very short time. Starting batteries have a large number of thin
plates for maximum surface area. The plates are composed of a Lead
"sponge", similar in appearance to a very fine foam sponge. This
gives a very large surface area, but if deep cycled, this sponge
will quickly be consumed and fall to the bottom of the cells.
Automotive batteries will generally fail after 30-150 deep cycles if
deep cycled, while they may last for thousands of cycles in normal
starting use (2-5% discharge).
- Deep cycle batteries are designed to be
discharged down as much as 80% time after time, and have much
thicker plates. The major difference between a true deep cycle
battery and others is that the plates are SOLID Lead plates - not
sponge. This gives less surface area, thus less "instant" power like
starting batteries need. Although these an be cycled down to 20%
charge, the best lifespan vs cost method is to keep the average
cycle at about 50% discharge.
- Unfortunately, it is often impossible to tell what you are
really buying in some of the discount stores or places that
specialize in automotive batteries. The golf car battery is quite
popular for small systems and RV's. The problem is that "golf car"
refers to a size of battery (commonly called GC-2, or T-105), not
the type or construction - so the quality and construction of a golf
car battery can vary considerably - ranging from the cheap off brand
with thin plates up the true deep cycle brands, such as Crown, Deka,
Trojan, etc. In general, you get what you pay for.
- Marine batteries are usually a "hybrid", and
fall between the starting and deep-cycle batteries, though a few
(Rolls-Surrette and Concorde, for example) are true deep cycle. In
the hybrid, the plates may be composed of Lead sponge, but it is
coarser and heavier than that used in starting batteries. It is
often hard to tell what you are getting in a "marine" battery, but
most are a hybrid. Starting batteries are usually rated at "CCA", or
cold cranking amps, or "MCA", Marine cranking amps - the same as
"CA". Any battery with the capacity shown in CA or MCA may or may
not be a true deep-cycle battery. It is sometimes hard to tell, as
the term deep cycle is often overused. CA
and MCA ratings are at 32 degrees F, while CCA is at zero degree F.
Unfortunately, the only positive way to tell with some batteries is
to buy one and cut it open - not much of an option.
There is generally no problem with this, providing that allowance is
made for the lower cranking amps compared to a similar
size starting battery. As a general rule, if you are going to use a true
deep cycle battery (such as the Concorde SunXtender) also as a starting
battery, it should be oversized about 20% compared to
the existing or recommended starting battery group size to get the same
cranking amps. That is about the same as replacing a group 24 with a
group 31. With modern engines with fuel injection and electronic
ignition, it generally takes much less battery power to crank and start
them, so raw cranking amps is less important than it used to be. On the
other hand, many cars, boats, and RV's are more heavily loaded with
power sucking "appliances", such as megawatt stereo systems etc. that
are more suited for deep cycle batteries. We have used the Concorde
SunXtender AGM batteries in some of our vehicles with no problems.
It will not hurt a deep cycle battery to be used as a starting
battery, but for the same size battery they cannot supply as much
cranking amps as a regular starting battery.
Nearly all large rechargeable batteries in common use are Lead-Acid
type. (There are some NiCads in use, but for most purposes the very high
initial expense, and the high expense of disposal, does not justify
them). The acid is typically 30% Sulfuric acid and 70% water at full
charge. NiFe (Nickel-Iron) batteries are also available - these have a
very long life, but rather poor efficiency (60-70%) and the voltages are
different, making it more difficult to match up with standard 12v/24/48v
systems and inverters. The biggest problem with NiFe batteries is that
you may have to put in 100 watts to get 70 watts of charge - they are
much less efficient than Lead-Acid. What you save on batteries you will
have to make up for by buying a larger solar panel system. NiCads are
also inefficient - typically around 65% - and very expensive. However,
NiCads can be frozen without damage, so are sometimes used in areas
where the temperatures may fall below -50 degrees F. Most AGM batteries
will also survive freezing with no problems, even though the output when
frozen will be little or nothing.
Sometimes called "fork lift", "traction" or "stationary" batteries,
are used where power is needed over a longer period of time, and are
designed to be "deep cycled", or discharged down as low as 20% of full
charge (80% DOD, or Depth of Discharge). These are often called traction
batteries because of their widespread use in forklifts, golf carts, and
floor sweepers (from which we get the "GC" and "FS" series of battery
sizes). Deep cycle batteries have much thicker plates than automotive
batteries.
Plate Thickness
Plate thickness (of the Positive plate) matters because of a factor
called "positive grid corrosion". This ranks among the top 3
reasons for battery failure. The positive (+) plate is what gets eaten
away gradually over time, so eventually there is nothing left - it all
falls to the bottom as sediment. Thicker plates are directly related to
longer life, so other things being equal, the battery with the thickest
plates will last the longest. The negative plate in batteries expands
somewhat during discharge, which is why nearly all batteries have
separators, such as glass mat or paper, that can be compressed.
Automotive batteries typically have plates about .040" (4/100")
thick, while forklift batteries may have plates more than 1/4" (.265"
for example in larger Rolls-Surrette) thick - almost 7 times as thick
as auto batteries. The typical golf cart will have plates that are
around .07 to .11" thick. The Concorde AGM's are .115", The Rolls-Surrette
L-16 type (CH460) is .150", and the US Battery and Trojan L-16 types are
.090". The Crown L-16HC size has .22" thick plates. While plate
thickness is not the only factor in how many deep cycles a battery can
take before it dies, it is the most important one.
Most industrial (fork lift) deep-cycle batteries use Lead-Antimony
plates rather than the Lead-Calcium used in AGM or gelled deep-cycle
batteries and in automotive starting batteries. The Antimony increases
plate life and strength, but increases gassing and water loss. This is
why most industrial batteries have to be checked often for water level
if you do not have Hydrocaps. The self discharge of
batteries with Lead-Antimony plates can be high - as much as 1% per day
on an older battery. A new AGM typically self-discharges at about 1-2%
per month, while an old one may be as much as 2% per week.
Sealed batteries are made with vents that (usually) cannot be
removed. The so-called Maintenance Free batteries are also sealed, but
are not usually leak proof. Sealed batteries are not totally sealed, as
they must allow gas to vent during charging. If overcharged too many
times, some of these batteries can lose enough water that they will die
before their time. Most smaller deep cycle batteries (including AGM) use
Lead-Calcium plates for increased life, while most industrial and
forklift batteries use Lead-Antimony for greater plate strength
to withstand shock and vibration.
Lead-Antimony (such as forklift and floor scrubber) batteries have a
much higher self-discharge rate (2-10% per week) than Lead or
Lead-Calcium (1-5% per month), but the Antimony improves the mechanical
strength of the plates, which is an important factor in electric
vehicles. They are generally used where they are under constant or very
frequent charge/discharge cycles, such as fork lifts and floor sweepers.
The Antimony increases plate life at the expense of higher self
discharge. If left for long periods unused, these should be trickle
charged to avoid damage from sulfation - but this applies to ANY
battery.
As in all things, there are trade offs. The Lead-Antimony types have
a very long lifespan, but higher self discharge rates.
Batteries come in all different sizes. Many have "group" sizes, which
is based upon the physical size and terminal placement. It is NOT
a measure of battery capacity. Typical BCI codes are group U1, 24, 27,
and 31. Industrial batteries are usually designated by a part number
such as "FS" for floor sweeper, or "GC" for golf cart. Many batteries
follow no particular code, and are just manufacturers part numbers.
Other standard size codes are 4D & 8D, large industrial batteries,
commonly used in solar electric systems.
Some common battery size codes used are: (ratings are
approximate)
| U1 |
34 to 40 Amp hours |
12 volts |
| Group 24 |
70-85 Amp hours |
12 volts |
| Group 27 |
85-105 Amp hours |
12 volts |
| Group 31 |
95-125 Amp hours |
12 volts |
| 4-D |
180-215 Amp hours |
12 volts |
| 8-D |
225-255 Amp hours |
12 volts |
| Golf Cart & T-105 |
180 to 225 Amp hours |
6 volts |
| L-16, L16HC etc. |
340 to 415 Amp hours |
6 volts |
Gelled batteries, or "Gel Cells" contain acid that has been "gelled"
by the addition of Silica Gel, turning the acid into a solid mass that
looks like gooey Jell-O. The advantage of these batteries is that it is
impossible to spill acid even if they are broken. However, there are
several disadvantages. One is that they must be charged at a slower rate
(C/20) to prevent excess gas from damaging the cells. They cannot be
fast charged on a conventional automotive charger or they may be
permanently damaged. This is not usually a problem with solar electric
systems, but if an auxiliary generator or inverter bulk charger is used,
current must be limited to the manufacturers
specifications. Most better inverters commonly used in solar electric
systems can be set to limit charging current to the batteries.
Some other disadvantages of gel cells is that they must be charged at
a lower voltage (2/10th's less) than flooded or AGM batteries. If
overcharged, voids can develop in the gel which will never heal, causing
a loss in battery capacity. In hot climates, water loss can be enough
over 2-4 years to cause premature battery death. It is for this and
other reasons that we no longer sell any of the gelled cells except for
replacement use. The newer AGM (absorbed glass mat) batteries have all
the advantages (and then some) of gelled, with none of the
disadvantages.
A newer type of sealed battery uses "Absorbed Glass Mats", or AGM
between the plates. This is a very fine fiber Boron-Silicate glass mat.
These type of batteries have all the advantages of gelled, but can take
much more abuse. We sell the Concorde (and Lifeline, made by Concorde)
AGM batteries. These are also called "starved electrolyte", as the mat
is about 95% saturated rather than fully soaked. That
also means that they will not leak acid even if broken.
AGM batteries have several advantages over both gelled and flooded,
at about the same cost as gelled:
Since all the electrolyte (acid) is contained in the glass mats, they
cannot spill, even if broken. This also means that since they are
non-hazardous, the shipping costs are lower. In addition, since there is
no liquid to freeze and expand, they are practically immune from
freezing damage.
Nearly all AGM batteries are "recombinant" - what that means
is that the Oxygen and Hydrogen recombine INSIDE the battery. These use
gas phase transfer of oxygen to the negative plates to recombine them
back into water while charging and prevent the loss of water through
electrolysis. The recombining is typically 99+% efficient, so almost no
water is lost.
The charging voltages are the same as for any standard battery - no
need for any special adjustments or problems with incompatible chargers
or charge controls. And, since the internal resistance is extremely low,
there is almost no heating of the battery even under heavy charge and
discharge currents. The Concorde (and most AGM) batteries have no charge
or discharge current limits.
AGM's have a very low self-discharge - from 1% to 3% per month is
usual. This means that they can sit in storage for much longer periods
without charging than standard batteries. The Concorde batteries can be
almost fully recharged (95% or better) even after 30 days of being
totally discharged.
AGM's do not have any liquid to spill, and even under severe
overcharge conditions hydrogen emission is far below the 4% max
specified for aircraft and enclosed spaces. The plates in AGM's are
tightly packed and rigidly mounted, and will withstand shock and
vibration better than any standard battery.
Even with all the advantages listed above, there is still a place for
the standard flooded deep cycle battery. AGM's will cost 2 to 3 times as
much as flooded batteries of the same capacity. In many installations,
where the batteries are set in an area where you don't have to worry
about fumes or leakage, a standard or industrial deep cycle is a better
economic choice. AGM batteries main advantages are no maintenance,
completely sealed against fumes, Hydrogen, or leakage, non-spilling even
if they are broken, and can survive most freezes. Not everyone needs
these features.
Battery capacity (how many amp-hours it can hold) is reduced as
temperature goes down, and increased as temperature goes up. This is why
your car battery dies on a cold winter morning, even though it worked
fine the previous afternoon. If your batteries spend part of the year
shivering in the cold, the reduced capacity has to be taken into account
when sizing the system batteries. The standard rating for batteries is
at room temperature - 25 degrees C (about 77 F). At approximately -22
degrees F (-27 C), battery AH capacity drops to 50%. At freezing,
capacity is reduced by 20%. Capacity is increased at higher temperatures
- at 122 degrees F, battery capacity would be about 12% higher.
Battery charging voltage also changes with
temperature. It will vary from about 2.74 volts per cell (16.4 volts) at
-40 C to 2.3 volts per cell (13.8 volts) at 50 C. This is why you should
have temperature compensation on your charger or charge control if your
batteries are outside and/or subject to wide temperature variations.
Some charge controls have temperature compensation built in (such as
Morningstar) - this works fine if the controller is subject to the same
temperatures as the batteries. However, if your batteries are outside,
and the controller is inside, it does not work that well. Adding another
complication is that large battery banks make up a large thermal
mass.
Thermal mass means that because they have so much mass, they
will change internal temperature much slower than the surrounding air
temperature. A large insulated battery bank may vary as little as 10
degrees over 24 hours internally, even though the air temperature varies
from 20 to 70 degrees. For this reason, external (add-on) temperature
sensors should be attached to one of the POSITIVE plate terminals, and
bundled up a little with some type of insulation on the terminal. The
sensor will then read very close to the actual internal battery
temperature.
Even though battery capacity at high temperatures is higher, battery
life is shortened. Battery capacity is reduced by 50% at -22
degrees F - but battery LIFE increases by about 60%. Battery life is
reduced at higher temperatures - for every 15 degrees F over 77, battery
life is cut in half. This holds true for ANY type of Lead-Acid battery,
whether sealed, gelled, AGM, industrial or whatever. This is actually
not as bad as it seems, as the battery will tend to average out the good
and bad times. Click on the small graph to see a full size chart of
temperature vs capacity.
One last note on temperatures - in some places that have extremely
cold or hot conditions, batteries may be sold locally that are NOT
standard electrolyte (acid) strengths. The electrolyte may be stronger
(for cold) or weaker (for very hot) climates. In such cases, the
specific gravity and the voltages may vary from what we show.
A battery "cycle" is one complete discharge and recharge cycle. It is
usually considered to be discharging from 100% to 20%, and then back to
100%. However, there are often ratings for other depth of discharge
cycles, the most common ones are 10%, 20%, and 50%. You have to be
careful when looking at ratings that list how many cycles a battery is
rated for unless it also states how far down it is being discharged. For
example, one of the widely advertised telephone type (float service)
batteries have been advertised as having a 20-year life. If you look at
the fine print, it has that rating only at 5% DOD - it is much less when
used in an application where they are cycled deeper on a regular basis.
Those same batteries are rated at less than 5 years if cycled to 50%.
For example, most golf cart batteries are rated for about 550 cycles to
50% discharge - which equates to about 2 years.
Battery life is directly related to how deep the
battery is cycled each time. If a battery is discharged to 50% every
day, it will last about twice as long as if it is cycled to 80% DOD. If
cycled only 10% DOD, it will last about 5 times as long as one cycled to
50%. Obviously, there are some practical limitations on this - you don't
usually want to have a 5 ton pile of batteries sitting there just to
reduce the DOD. The most practical number to use is 50% DOD on a regular
basis. This does NOT mean you cannot go to 80% once in a while. It's
just that when designing a system when you have some idea of the loads,
you should figure on an average DOD of around 50% for
the best storage vs cost factor. Also, there is an upper limit - a
battery that is continually cycled 5% or less will usually not last as
long as one cycled down 10%. This happens because at very shallow
cycles, the Lead Dioxide tends to build up in clumps on the the positive
plates rather in an even film. The graph above shows how lifespan is
affected by depth of discharge. The chart is for a Concorde Lifeline
battery, but all lead-acid batteries will be similar in the shape of the
curve, although the number of cycles will vary.
All Lead-Acid batteries supply about 2.14 volts per cell (12.6
to 12.8 for a 12 volt battery) when fully charged. Batteries that are
stored for long periods will eventually lose all their charge. This
"leakage" or self discharge varies considerably with battery type, age,
& temperature. It can range from about 1% to 15% per month. Generally,
new AGM batteries have the lowest, and old industrial (Lead-Antimony
plates) are the highest. In systems that are continually connected to
some type charging source, whether it is solar, wind, or an AC powered
charger this is seldom a problem. However, one of the biggest killers of
batteries is sitting stored in a partly discharged state for a few
months. A "float" charge should be maintained on the batteries even if
they are not used (or, especially if they are not
used). Even most "dry charged" batteries
(those sold without electrolyte so they can be shipped more easily, with
acid added later) will deteriorate over time. Max storage life on those
is about 2-3 years.
Batteries self-discharge faster at higher temperatures. Lifespan can
also be seriously reduced at higher temperatures - most manufacturers
state this as a 50% loss in life for every 15 degrees F over a 77 degree
cell temperature. Lifespan is increased at the same rate if below 77
degrees, but capacity is reduced. This tends to even out in most systems
- they will spend part of their life at higher temperatures, and part at
lower.
Myth: The old myth about not storing
batteries on concrete floors is just that - a myth. This story has been
around for 100 years, and originated back when battery cases were made
up of wood and asphalt. The acid would leak from them, and form a
slow-discharging circuit through the now acid-soaked and conductive
floor.
State of Charge
State of charge, or conversely, the depth of discharge (DOD)
can be determined by measuring the voltage and/or the specific gravity
of the acid with a hydrometer. This will NOT tell you how good (capacity
in AH) the battery condition is - only a sustained load test
can do that. Voltage on a fully charged battery will read 2.12 to 2.15
volts per cell, or 12.7 volts for a 12 volt battery. At 50% the reading
will be 2.03 VPC (Volts Per Cell), and at 0% will be 1.75 VPC or less.
Specific gravity will be about 1.265 for a fully charged cell, and 1.13
or less for a totally discharged cell. This can vary with battery types
and brands somewhat - when you buy new batteries you should charge them
up and let them sit for a while, then take a reference measurement. Many
batteries are sealed, and hydrometer reading cannot be taken, so you
must rely on voltage. Hydrometer readings may not tell the whole story,
as it takes a while for the acid to get mixed up in wet cells. If
measured right after charging, you might see 1.27 at the top of the
cell, even though it is much less at the bottom. This does not apply to
gelled or AGM batteries.
"False" Capacity
A battery can meet the voltage tests for being at full charge, yet be
much lower than it's original capacity. If plates are damaged, sulfated,
or partially gone from long use, the battery may give the
appearance of being fully charged, but in reality acts like a
battery of much smaller size. This same thing can occur in gelled cells
if they are overcharged and gaps or bubbles occur in the gel. What is
left of the plates may be fully functional, but with only 20% of the
plates left... Batteries usually go bad for other reasons before
reaching this point, but it is something to be aware of if your
batteries seem to test OK but lack capacity and go dead very quickly
under load.
On the table below, you have to be careful that you are not just
measuring the surface charge. To properly check the voltages, the
battery should sit at rest for a few hours, or you should put a small
load on it, such as a small automotive bulb, for a few minutes. The
voltages below apply to ALL Lead-Acid batteries, except gelled. For gel
cells, subtract .2 volts. Note that the voltages when actually
charging will be quite different, so do not use these numbers
for a battery that is under charge.
All deep cycle batteries are rated in amp-hours. An amp-hour is one
amp for one hour, or 10 amps for 1/10 of an hour and so forth. It is
amps x hours. If you have something that pulls 20 amps,
and you use it for 20 minutes, then the amp-hours used would be 20
(amps) x .333 (hours), or 6.67 AH. The accepted AH rating time period
for batteries used in solar electric and backup power systems (and for
nearly all deep cycle batteries) is the "20 hour rate".
This means that it is discharged down to 10.5 volts over a 20 hour
period while the total actual amp-hours it supplies is measured.
Sometimes ratings at the 6 hour rate and 100 hour rate are
also given for comparison and for different applications. The 6-hour
rate is often used for industrial batteries, as that is a typical daily
duty cycle. Sometimes the 100 hour rate is given just to make the
battery look better than it really is, but it is also useful for
figuring battery capacity for long-term backup amp-hour requirements.
Why amp-hours are specified at a particular rate:
Because of something called the
Peukert Effect. The Peukert value is directly related to the
internal resistance of the battery. The higher the internal resistance,
the higher the losses while charging and discharging, especially at
higher currents. This means that the faster a battery is used
(discharged), the LOWER the AH capacity. Conversely, if it is drained
slower, the AH capacity is higher. This is important because some
manufacturers and vendors have chosen to rate their batteries at the 100
hour rate - which makes them look a lot better than they really are.
Here are some typical battery capacities from the manufacturers data
sheets:
| Battery Type |
100 hour rate |
20 hour rate |
8 |
| Trojan T-105 |
250 AH |
225 AH |
n/a |
| US Battery
2200 |
n/a |
225 AH |
181 AH |
| Concorde
PVX-6220 |
255 AH |
221 AH |
183 AH |
| Surrette S-460
(L-16) |
429 AH |
344 AH |
282 AH |
| Trojan L-16 |
400 AH |
360 AH |
n/a |
| Surrette
CS-25-PS |
974 AH |
779 AH |
639 AH |
State of Charge
Here are no-load typical voltages vs state of charge
(figured at 10.5 volts = fully discharged, and 77 degrees F).
Voltages are for a 12 volt battery system. For 24 volt systems multiply
by 2, for 48 volt system, multiply by 4. VPC is the volts per individual
cell - if you measure more than a .2 volt difference between each cell,
you need to equalize, or your batteries are going bad, or they may be
sulfated. These voltages are for batteries that have been at rest for 3
hours or more. Batteries that are being charged will be higher - the
voltages while under charge will not tell you anything, you have to let
the battery sit for a while. For longest life, batteries should stay in
the green zone. Occasional dips into the yellow are not harmful, but
continual discharges to those levels will shorten battery life
considerably. It is important to realize that voltage measurements
are only approximate. The best determination is to measure the
specific gravity, but in many batteries this is difficult or impossible.
Note the large voltage drop in the last 10%.
| State of
Charge |
12 Volt
battery |
Volts per
Cell |
| 100% |
12.7 |
2.12 |
| 90% |
12.5 |
2.08 |
| 80% |
12.42 |
2.07 |
| 70% |
12.32 |
2.05 |
| 60% |
12.20 |
2.03 |
| 50% |
12.06 |
2.01 |
| 40% |
11.9 |
1.98 |
| 30% |
11.75 |
1.96 |
| 20% |
11.58 |
1.93 |
|
10% |
11.31 |
1.89 |
|
0 |
10.5 |
1.75 |
Battery charging takes place in 3 basic stages:
Bulk, Absorption, and Float.
Bulk Charge - The first stage of
3-stage battery charging. Current is sent to batteries at the maximum
safe rate they will accept until voltage rises to near (80-90%) full
charge level. Voltages at this stage typically range from 10.5 volts to
15 volts. There is no "correct" voltage for bulk charging, but there may
be limits on the maximum current that the battery and/or wiring can
take.
Absorption Charge: The 2nd stage of 3-stage
battery charging. Voltage remains constant and current gradually tapers
off as internal resistance increases during charging. It is during this
stage that the charger puts out maximum voltage. Voltages at this stage
are typically around 14.2 to 15.5 volts.
Float Charge: The 3rd stage of 3-stage battery charging. After
batteries reach full charge, charging voltage is reduced to a lower
level (typically 12.8 to 13.2) to reduce gassing and prolong battery
life. This is often referred to as a maintenance or trickle charge,
since it's main purpose is to keep an already charged battery from
discharging. PWM, or "pulse width modulation" accomplishes the same
thing. In PWM, the controller or charger senses tiny voltage drops in
the battery and sends very short charging cycles (pulses) to the
battery. This may occur several hundred times per minute. It is called
"pulse width" because the width of the pulses may vary from a few
microseconds to several seconds. Note that for long term float
service, such as backup power systems that are seldom discharged, the
float voltage should be around 13.02 to 13.20 volts.
Chargers: Most garage and consumer (automotive) type battery
chargers are bulk charge only, and have little (if any) voltage
regulation. They are fine for a quick boost to low batteries, but not to
leave on for long periods. Among the regulated chargers, there are the
voltage regulated ones, such as Iota Engineering and Todd, which keep a
constant regulated voltage on the batteries. If these are set to the
correct voltages for your batteries, they will keep the batteries
charged without damage. These are sometimes called "taper charge" - as
if that is a selling point. What taper charge really means is that as
the battery gets charged up, the voltage goes up, so the amps out of the
charger goes down. They charge OK, but a charger rated at 20 amps may
only be supplying 5 amps when the batteries are 80% charged. To get
around this, Statpower (and maybe others?) have come out with "smart",
or multi-stage chargers. These use a variable voltage to keep the
charging amps much more constant for faster charging.
A charge controller is a regulator that goes between the
solar panels and the batteries. Regulators for solar systems are
designed to keep the batteries charged at peak without overcharging.
Meters for Amps (from the panels) and battery Volts are optional with
most types. Some of the various brands and models that we use and
recommend are listed below. Note that a couple of them are listed as
"power trackers" - for a full explanation of this, see our page on "Why
120 watts does not equal 120 watts".
Most of the modern controllers have automatic or manual
equalization built in, and many have a LOAD output. There is no "best"
controller for all applications - some systems may need the bells and
whistles of the more expensive controls, others may not.
These are some of the charge controllers that we
recommend, but almost any modern controller will work fine. Exact
model will depend on application and system size and voltage.
Xantrex (All)
Morningstar (All)
Outback Power MX60 & 80
Blue Sky Energy (Solar Boost)
Steca
Using any of these will almost always give better
battery life and charge than "on-off" or simple shunt type regulators
Battery Charging Voltages and Currents:
Most flooded batteries should be charged at no more than
the "C/8" rate for any sustained period. "C/8" is the battery capacity
at the 20-hour rate divided by 8. For a 220 AH battery, this would equal
26 Amps. Gelled cells should be charged at
no more than the C/20 rate, or 5% of their amp-hour capacity. The
Concorde AGM batteries are a special case - the can be charged at up
the the Cx4 rate, or 400% of the capacity for the bulk charge cycle.
However, since very few battery cables can take that much current, we
don't recommend you try this at home. To avoid cable overheating, you
should stick to C/4 or less.
Charging at 15.5 volts will give you a 100% charge on
Lead-Acid batteries. Once the charging voltage reaches 2.583 volts per
cell, charging should stop or be reduced to a trickle charge. Note that
flooded batteries MUST bubble (gas) somewhat to insure a full
charge, and to mix the electrolyte. Float voltage for Lead-Acid
batteries should be about 2.15 to 2.23 volts per cell, or about
12.9-13.4 volts for a 12 volt battery. At higher temperatures (over 85
degrees F) this should be reduced to about 2.10 volts per cell.
Never add acid to a battery except to replace spilled liquid.
Distilled or deionized water should be used to top off non-sealed
batteries. Float and charging voltages for gelled batteries are usually
about 2/10th volt less than for flooded to reduce water loss. Note that
many shunt-type charge controllers sold for solar systems will NOT give
you a full charge - check the specifications first. To get a full
charge, you must continue to apply a current after the battery voltage
reaches the cutoff point of most of these type of controllers. This is
why we recommend the charge controls and battery chargers listed in the
sections above. Not all shunt type controllers are 100% on or off, but
most are.
Flooded battery life can be extended if an equalizing charge
is applied every 10 to 40 days. This is a charge that is about 10%
higher than normal full charge voltage, and is applied for about 2 to 16
hours. This makes sure that all the cells are equally charged, and the
gas bubbles mix the electrolyte. If the liquid in standard wet cells is
not mixed, the electrolyte becomes "stratified". You can have very
strong solution at the bottom, and very weak at the top of the cell.
With stratification, you can test a battery with a hydrometer and get
readings that are quite a ways off. If you cannot equalize for some
reason, you should let the battery sit for at least 24 hours and then
use the hydrometer. AGM and gelled should be equalized 2-4 times a year
at most - check the manufacturers recommendations, especially on gelled.
Battery Aging
As batteries age, their maintenance requirements change.
This means longer charging time and/or higher finish rate (higher
amperage at the end of the charge). Usually older batteries need to be
watered more often. And, their capacity decreases.
Nearly all batteries will not reach full capacity until
cycled 10-30 times. A brand new battery will have a capacity of about
5-10% less than the rated capacity.
Batteries should be watered after charging unless
the plates are exposed, then add just enough water to cover the plates.
After a full charge, the water level should be even in all cells and
usually 1/4" to 1/2" below the bottom of the fill well in the cell
(depends on battery size and type).
In situations where multiple batteries are connected in
series, parallel or series/parallel, replacement batteries should be the
same size, type and manufacturer (if possible). Age and usage level
should be the same as the companion batteries. Do not put a new battery
in a pack which is more than 6 months old or has more than 75 cycles.
Either replace with all new or use a good used battery. For long life
batteries, such as the Surrette and Crown, you can have up to a one year
age difference.
The vent caps on flooded batteries should remain on the
battery while charging. This prevents a lot of the water loss and
splashing that may occur when they are bubbling.
When you first buy a new set of flooded (wet) batteries,
you should fully charge and equalize them, and then take a hydrometer
reading for future reference. Since not all batteries have exactly the
same acid strength, this will give you a baseline for future readings.
When using a small solar panel to keep a float
(maintenance) charge on a battery (without using a charge controller),
choose a panel that will give a maximum output of about 1/300th to
1/1000th of the amp-hour capacity. For a pair of golf cart batteries,
that would be about a 1 to 5 watt panel - the smaller panel if you get 5
or more hours of sun per day, the larger one for those long cloudy
winter days in the Northeast.
Lead-Acid batteries do NOT have a memory, and the rumor
that they should be fully discharged to avoid this "memory" is totally
false and will lead to early battery failure.
Inactivity can be extremely harmful to a battery. It is
a VERY poor idea to buy new batteries and "save" them for later.
Either buy them when you need them, or keep them on a continual trickle
charge. The best thing - if you buy them, use them.
Only clean water should be used for cleaning the outside
of batteries. Solvents or spray cleaners should not be used.
Some Peukert Exponent values (not complete, just for
info). We don't have a lot of data. Trojan T-105 = 1.25; Optima 750S =
1.109; US Battery 2200 = 1.20.More information - Manufacturers Websites
US Battery
Manufacturing Company - some good information and data.
Crown
Battery - A major manufacturer of industrial and deep cycle
batteries.
Trojan Battery
- not a lot of real technical info here, but has all the specifications.
Exide - not
much here but marketing stuff, but you can buy Exide T-shirts. We don't
sell Exide.
Surrette - Specs
and data on the Surrette deep cycle and marine batteries
Concorde
- specs and data on all the Concorde batteries, including Lifeline.
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